Wrap-up
88%
Surface treatment sequencing: nitride, PVD, polish, in what order
The build order that takes an H13 forge die from rough block to coated, polished, ready-to-run, and why getting any step out of sequence is a failure mode rather than a slow ramp to nominal life.
Tying it together
What this means on the shop floor
Aluminum forge dies in H13 get the full duplex sequence. Plasma nitride to 0.20-0.30 mm with a compound layer of 6-8 µm. Polish step two takes the compound layer to 3-5 µm. AlTiN deposited at 3-5 µm. Skipping the nitride and going straight to PVD is the most common mistake on aluminum work and the source of the early-spall failure pattern.
Steel hot-forge dies running below 80,000 cycles get nitride only. Premium H13 (ESR) at 48 HRC, plasma nitride to 0.40 mm, compound layer 5-8 µm γ'-dominant, no PVD.
Hot-trim dies on scaled billet get duplex when sliding wear against oxide debris is the binding constraint.
Impact-dominated drop-forge dies get nitride only, thick diffusion zone, thin γ' compound layer, no PVD. The coating chips off under impact regardless of the substrate underneath.
Pushback questions for the vendor
- What is the compound layer thickness target on the cavity, and is the polish step two removal budgeted into that target?
- If we are quoting duplex, what is the failure mode you are targeting with the PVD layer, and is the substrate hard enough at the coating interface to prevent eggshell collapse?
- What is your masking plan for the parting line and reference surfaces, and is masking specified on the drawing or only in the routing?
- What is the cleanliness handoff between the nitride house and the coater, and who owns the part during the gap?
Common confusions
PVD without nitride is not a faster duplex. The PVD is sitting on an eggshell and the die fails by spalling, not by wear.
"Polish to mirror finish" is not a nitride spec. Specify Ra targets and material removal limits in microns. A polisher chasing visual finish removes whatever depth the surface needed, which on a nitrided cavity often means breaching the compound layer.
A nitride compound layer is not a coating. It is a metallurgical case grown into the substrate. Treating it as a coating in the routing leads to spec errors, such as "remove the coating before PVD" when the correct call is "polish the compound layer to 3 µm before PVD."
Duplex is not "more is better." It is targeted protection against a specific wear mode. If the failure mode is thermal-fatigue cracking, duplex does not extend life and may shorten it.
Up next: polishing and surface finish.
Sources
- ScienceDirect, Influence of the structure of the composite 'nitrided layer / PVD coating' on the durability of forging dies made of steel DIN-1.2367, Surface and Coatings Technology. https://www.sciencedirect.com/science/article/abs/pii/S0257897203012362
- ScienceDirect, Improvement of hot forging manufacturing with PVD and DUPLEX coatings, Surface and Coatings Technology. https://www.sciencedirect.com/science/article/abs/pii/S0257897200011154
- Ionbond (IHI), Duplex Coatings Lesson 1: The Correct Heat Treatment of Tool Steels. https://www.ionbond.com/coating-services/forming-molding-tools/ionbond-summer-school-duplex-coatings/duplex-coatings-lesson-1-the-correct-heat-treatment-of-tool-steels/
- Oerlikon Balzers, BALINIT product family for forming and forging tools. https://www.oerlikon.com/balzers/com/en/portfolio/balzers-surface-solutions/pvd-and-pacvd-based-coatings/balinit/
- voestalpine eifeler, Duplex Treatment. https://www.eifeler.com/en/services/duplex-treatment/
- Advanced Heat Treat Corp / Forging Magazine, Enhancing Forging Dies Durability with Ion Nitriding. https://www.ahtcorp.com/articles/blog/enhancing-forging-dies-durability-with-ion-nitriding/
- Cogdill, I. A Forging Engineer's Guide to Modern Nitride Case Hardening for H13 Dies. https://www.isaaccogdill.com/forging/forge-die-nitriding-method-comparison
- ASM International, ASM Handbook Volume 5: Surface Engineering. https://dl.asminternational.org/handbooks/book/13/Volume-5-Surface-Engineering